Researchers Explore Construction 3D Printing with Calcined Clay

Share this Article

While industries such as medicine, aerospace, and automotive often seem to steal the wow factor within the 3D printing spotlight, the construction zone has certainly not disappointed in terms of spectacular headlines. And as a wide range of materials continue to prove themselves, cement has certainly been no slouch; in fact, you could spend many hours poring over the different types of research involving both cement and additive manufacturing—from experimentation with self-reinforced strain hardening composites, spray-based materials, and even self-healing systems.

Now, researchers are studying how varied calcined clay affects cement for 3D printing, with their findings released in “Effect of different grade levels of calcined clays on fresh and hardened properties of ternary-blended cementitious materials for 3D printing.” Pointing out that concrete is often used in both particle bed- and extrusion-based 3D concrete printing (3DCP), the authors consider extrusion to be more suitable for the large scale.

While printability, buildability, and extrudability are key, other factors are necessary for quality extrusion, such as high fluidibility, low viscosity, and suitable layer adhesion. Most studies regarding cement include additives like ash, limestone, silica, and slag—offering improved sustainability with decreased use of Portland cement; however, with pressure on the additives now too, they are becoming more depleted.

Calcined clay is clay that has been converted into a ceramic via firing in a kiln up to 1500 degrees Fahrenheit. The material is most often used as a soil amendment on baseball fields. Previous research has pointed to calcined clay as a good alternative due to:

  • Low CO2footprint
  • Abundant raw materials
  • Good compressive strength
  • Capillary porosity refinement with pozzolanic reactions

Calcined clay may be prone to unpredictability though, due to manufacturer variances in production, as well as deviances caused by temperature, differences due to the structure and purity of raw materials, and more—along with reactivity dependent on metakaolin (MK).

During this study, the authors discovered that in experimenting with two different types of calcined clays (a low-grade calcined clay (LGCC) from France, containing 50% MK, and another from the US, made up of 95% MK—and considered to be “high-grade”) they were able to improve the cementitious mixture to the point of comparing with plain cement paste. This coincides with other research showing that fresh mixtures can be transformed with the addition of calcined clay, but very little has been performed overall in terms of study.

Physical characteristics and oxide composition from XRF of dry components in binders.

In ram extrusion testing (made up of a barrel, piston, stand, and an orifice, assembled in a servo-hydraulic Instron machine), they were able to change the MK content as well as the properties of the fresh mixture.

(a) Schematic drawing of the ram extruder; (b) Diagram of the orifice entrance flow region in a spherical coordinate system, according to Ref. [26,27]; (c) A typical trial of the ram extrusion test – predefined piston moving speed vs. displacement.

Piston speed (V0) and computed material flow rate (V) at the orifice.

A 3D printing test was performed on a “lab-scale 3DCP setup” at Delft University of Technology (TU Delft), made up of a three-degree freedom Computer Numerical Control (CNC) machine and a PFT Swing-M type conveying pump. Compressive strength after one week was reliant on hydration and the composition of the fresh mixtures while “at rest.” Air void content increased as they added high-grade calcined clay (HGCC) to cylindrical samples constructed from the upmost two layers of 3D printed beams

A lab-scale 3DCP setup at TU Delft. It consists of a CNC table, a conveying pump, a material hose, and a printhead (nozzle).

(a) Nozzle 1 with a rectangle opening (40 × 13.5 mm2); (b) Nozzle 2 with a round opening (Ø 15 mm).

“The results also confirmed that fresh mixtures with good buildability might be vulnerable to the formation of cold joint/weak interface between two adjacent layers,” said the researchers.

Printability window various with the HGCC substitution in calcined clay.

Buildability test results of method 1: (a) Buildability performance of mixtures LCC, MCC, and HCC; (b) Height and layer number of the printed object by using different mixtures (mixtures LCC and MCC: data recorded before collapse; mixture HCC: data recorded after the 21st layer); (c) Possible reasons for collapse of the rising structure.

[Source / Images: ‘Effect of different grade levels of calcined clays on fresh and hardened properties of ternary-blended cementitious materials for 3D printing’]


Share this Article

Recent News

3D Printing News Briefs, September 26, 2020: Nanoscribe, Azul 3D, Arburg

3D Printing Functionally Graded Materials Gets an F


3D Design

3D Printed Art

3D Printed Food

3D Printed Guns

You May Also Like

3D Printing Design for Automotive to Be Supported by Lehvoss & FENA

3D printing materials provider Lehvoss North America, part of the LEHVOSS Group of chemical companies operating under parent company Lehmann&Voss&Co., announced that it is partnering up with Forward Engineering North...

TOffeeAM raises £1 million for AI Topology Optimization Tool for 3D Printing

TOffeeAM, launched from Imperial College’s Techcelerate program, recently secured £1 million in seed funding. The funding was primarily led by IQ Capital, together with Entrepreneur First, the Royal Academy of...

3D Printing Webinar & Virtual Event Roundup, June 5, 2020

In this week’s webinar and virtual event roundup, we’ve got three webinars to share with you, one of which has already taken place but can be viewed by interested parties...

MELD Manufacturing Reaches Major Milestone with Metal 3D Printed Components

Virginia-based company MELD Manufacturing Corporation was launched in the spring of 2018 as a subsidiary of Aeroprobe Corporation, which produces instruments that provide and measure real-time air and flow data. Aeroprobe...


View our broad assortment of in house and third party products.