While industries such as medicine, aerospace, and automotive often seem to steal the wow factor within the 3D printing spotlight, the construction zone has certainly not disappointed in terms of spectacular headlines. And as a wide range of materials continue to prove themselves, cement has certainly been no slouch; in fact, you could spend many hours poring over the different types of research involving both cement and additive manufacturing—from experimentation with self-reinforced strain hardening composites, spray-based materials, and even self-healing systems.
Now, researchers are studying how varied calcined clay affects cement for 3D printing, with their findings released in “Effect of different grade levels of calcined clays on fresh and hardened properties of ternary-blended cementitious materials for 3D printing.” Pointing out that concrete is often used in both particle bed- and extrusion-based 3D concrete printing (3DCP), the authors consider extrusion to be more suitable for the large scale.
While printability, buildability, and extrudability are key, other factors are necessary for quality extrusion, such as high fluidibility, low viscosity, and suitable layer adhesion. Most studies regarding cement include additives like ash, limestone, silica, and slag—offering improved sustainability with decreased use of Portland cement; however, with pressure on the additives now too, they are becoming more depleted.
Calcined clay is clay that has been converted into a ceramic via firing in a kiln up to 1500 degrees Fahrenheit. The material is most often used as a soil amendment on baseball fields. Previous research has pointed to calcined clay as a good alternative due to:
- Low CO2footprint
- Abundant raw materials
- Good compressive strength
- Capillary porosity refinement with pozzolanic reactions
Calcined clay may be prone to unpredictability though, due to manufacturer variances in production, as well as deviances caused by temperature, differences due to the structure and purity of raw materials, and more—along with reactivity dependent on metakaolin (MK).
During this study, the authors discovered that in experimenting with two different types of calcined clays (a low-grade calcined clay (LGCC) from France, containing 50% MK, and another from the US, made up of 95% MK—and considered to be “high-grade”) they were able to improve the cementitious mixture to the point of comparing with plain cement paste. This coincides with other research showing that fresh mixtures can be transformed with the addition of calcined clay, but very little has been performed overall in terms of study.
In ram extrusion testing (made up of a barrel, piston, stand, and an orifice, assembled in a servo-hydraulic Instron machine), they were able to change the MK content as well as the properties of the fresh mixture.
A 3D printing test was performed on a “lab-scale 3DCP setup” at Delft University of Technology (TU Delft), made up of a three-degree freedom Computer Numerical Control (CNC) machine and a PFT Swing-M type conveying pump. Compressive strength after one week was reliant on hydration and the composition of the fresh mixtures while “at rest.” Air void content increased as they added high-grade calcined clay (HGCC) to cylindrical samples constructed from the upmost two layers of 3D printed beams
[Source / Images: ‘Effect of different grade levels of calcined clays on fresh and hardened properties of ternary-blended cementitious materials for 3D printing’]
“The results also confirmed that fresh mixtures with good buildability might be vulnerable to the formation of cold joint/weak interface between two adjacent layers,” said the researchers.
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