AMS Spring 2023

New 3D Printing Technology Enhances Performance of Patterned Polymer Membranes

6K SmarTech

Share this Article

3dp_3ds_pennstate_penn_logoIon exchange membranes, which are flat sheet-like materials that transport dissolved ions across a conductive polymeric membrane, are utilized in variety of energy applications. Used in fuel cells, particular batteries, water purification, desalination, food processing and much more, these membranes work to transport ions from one solution to another. Researchers from Penn State University’s Department of Materials Science and Engineering have just developed a new type of 3D printing process that is aimed at enhancing the hydrodynamic properties of these membranes, which would lead to improved ion transportation and mitigate fouling.

The most efficient way to enhance these properties is to make the membranes patterned, or profiled, which is traditionally done with a painstaking technique that involves etching a silicon mold with the desired pattern, pouring in the polymer, and waiting until it hardens. Even then, the outcome of this time-consuming and cost-prohibitive process is a single pattern type, which still brings about limitations in the functioning of the membrane.

membraneThe Penn State research team has developed a unique 3D printing technique to help enhance the properties of these ion exchange membranes. To place performance enhancing 3D patterns onto these 2D membranes, the researchers created a custom 3D photolithographic printing process, which is conceptually similar to stereolithography. The process involves a photocurable mixture of ionic polymers, which is exposed under a light projector that hardens the base layer. More polymer is then added to the base layer, which is selectively hardened using a projected pattern. The result of the process is a surface pattern that increases the conductivity of the membrane by as much as a factor of two or three.

By utilizing 3D printing to help fabricate custom-synthesized ion exchange membranes, the research team is able to rapidly produce whichever pattern they need to enhance the hydrodynamic properties and improve the function of the membrane. According to Jiho Seo, a PhD candidate in materials science and engineering and the lead author of this recent study, this is the first known example of using 3D printing to help create patterned membrane structures.

Michael Hickner, associate professor of materials science and engineering

Michael Hickner, Associate Professor of Materials Science and Engineering

“While surface patterned membranes have been studied previously, this is the first 3D printed example of these structures and the first model that really explains the resistance decrease in a quantitative way,” Seo said. “A simple parallel resistance model describes the effect of the pattern on lowering the resistance of these new membranes. This insight gives us a design tool to continue to innovate and create new patterns for further improvements along with changing the intrinsic chemistry of the material.”

The research findings were recently published in the American Chemical Society’s journal ACS Applied Materials and Interfaces, entitled “3D Printing of Micro-patterned Anion Exchange Membranes.” Supervised by Michael Hickner, Associate Professor of Materials Science and Engineering at Penn State, the research team will continue to investigate the different geometries and chemistries of the membranes they produce, and will also work on printing with new materials, both related to this membrane research and beyond. Aside from Seo and Hickner, PhD student Douglas Kushner also contributed to the published research. Discuss this project over in the 3D Printed Membranes forum at 3DPB.com.

Share this Article


Recent News

DMG Mori and Illinois Tech Announce Plans for National Center for Advanced Manufacturing

3D Printing News Unpeeled: Cellulose Nanocrystal PLA Bone Scaffolds, CraftBot and Zellerfeld



Categories

3D Design

3D Printed Art

3D Printed Food

3D Printed Guns


You May Also Like

The Women Trailblazing the Tiktok 3D Printing Scene, Part 1

3D printing was once only seen as a technology reserved only for professionals. It was difficult and expensive to obtain a system before desktop 3D printers began proliferating at the...

Featured

A First-Timer’s “Definitive” Guide to Surviving Formnext

Believe it or not, this year was my very first time attending the additive manufacturing (AM) industry powerhouse event known as formnext, which has been held in Germany for eight...

Desktop 3D Printer from Quantica Opens New Inkjet 3D Printing Possibilities

When we met Quantica at RAPID + TCT this year, we were so impressed with its inkjet 3D printing technology that we quickly invited Founder Ben Hartkopp onto the 3DPOD...

3D Printing Webinar and Event Roundup: October 30, 2022

We’re ramping up again in this week’s roundup, with several events taking place, including ICAM 2022, DEVELOP3D Live, ASME’s AM Medical Summit, and more. In terms of webinars, Stratasys and...