Metal Binder Jetting
Automotive Polymers

Romanian Researchers Create Promising Polysaccharide-Based 3D Printing Inks & Additives

Share this Article

Researchers from Romania have recently delved further into materials associated with 3D printing, outlining their findings in ‘Polysaccharide-Based 3D Printing Inks Supplemented with Additives.’ In this study, they combined a variety of different polysaccharides to improve 3D printing inks.

“A wide range of materials have shown potential in 3D printing but modeling these materials into self-supporting items with tunable mechanical properties, degradation, and suitable rheological response is still an issue,” explain the authors, as they introduce us to the process of creating new inks, beginning with refining wettability.

Wetting agents—or humectants—also reduce the contact angle between bioink and the printer nozzle, as well as decreasing the chances for drying or crusting.

Typical humectants include:

  • Polyethylene glycol (PEG)
  • Glycerol (Gly)
  • Sorbitol
  • Urea

In this study, the researchers created a ‘promising ink formulation’ based on CMC/Alg and CN/Alg, using wetting agents derived from both small and low-molecular weight polymers.

“Printing inks were formulated by using two precursor mixtures, CMC:Alg and CN:Alg in 1:1 mass ratio. For the first mentioned formulations, a solution of 4% CMC was prepared in distilled water and the corresponding amount of Alg was added under gentle stirring,” explained the researchers. “The latter formulations were obtained by directly dissolving Alg within CN suspension.”

Inks were printed using the 3D Discovery bioprinter from RegenHU. 3D printing experiments were performed, along with bioprinting of hydrogel scaffolds. BioCADTM software was used to create the G-code for the 3D constructs used in the study.

While Alg is not the best option for 3D direct writing on its own, CMC and CN ‘enhanced’ viscosity, better cross-linking occurred, and the -OH groups present offered a positive effect over solubility, and both rheological and mechanical behavior.

Schematic representation of the fibrillary organization of cellulose
before and after oxidation process

“Both cellulose types used herein, CMC and CN, differ greatly with respect to chemical and morphological features and yet both present favorable printing behavior,” stated the researchers.

Overall, rheological evaluation by the researchers stated that CMS compositions possessed low viscosity, flowing immediately upon stress. High-viscosity drops required ‘adequate external forces’ to engage the printing process.

“Loading an additional compound (such as PEG and glycerol) suggested the improvement of the wetting properties leading to slightly lower filament diameters relative to the corresponding reference composition,” stated the researchers.

“Considering the printing performance with respect to the predesigned architecture it can be concluded that a successful 3D printing was achieved using glycerol in the ink composition. Therefore, the fabrication of 3D scaffolds using a cellulosic material combined with alginate and a suitable additive provide accurate geometries but also guide the applications of the obtained hybrid hydrogels in the biomedical field.”

Researchers around the world are creating bioinks and hydrogels in labs, using materials meant to encourage tissue engineering of the liver, corneas, and more. What do you think of this news? Let us know your thoughts! Join the discussion of this and other 3D printing topics at 3DPrintBoard.com.

TEM images of CN

[Source / Images: ‘Polysaccharide-Based 3D Printing Inks Supplemented with Additives’]

Share this Article


Recent News

3D Printing News Unpeeled, Live with Joris Peels – Wednesday 10th of August

3D Printing News Briefs, August 10, 2022: Events, Awards, & More



Categories

3D Design

3D Printed Art

3D Printed Food

3D Printed Guns


You May Also Like

3D Printed Biocomposites Could Help Reduce Marine Plastic Pollution

Concerns about the impact of plastic litter and microplastics in the oceans are at the forefront of environmental study. For decades, the marine environment has suffered from the degradation of...

Featured

Markforged Buys Digital Metal: What Does it Mean for the 3D Printing Industry?

It’s been a few months since the additive manufacturing (AM) industry had a notable corporate acquisition, which seems like an eternity after all the competitive consolidation and shakeup we saw...

Black Buffalo Partners with Xerox to Finance Client’s Construction 3D Printing Purchases

Black Buffalo 3D, an emerging additive construction (AC) startup, announced a strategic partnership with FITTLE, Xerox’s equipment financing arm. Through the alliance, FITTLE will help make it easier for Black...

3D Printing News Briefs, July 21, 2022: Layoffs, Heat Exchangers, & More

In today’s 3D Printing News Briefs, starting with business, manufacturing company Fast Radius recently cut 20% of its workforce. Then, Xometry has introduced new digital sourcing tools and more. A...