Researchers have used 3D printing to create force sensors they say they couldn’t build with any other existing technology. The polymer structures change color when stretched, and the more they’re distorted, the more the color changes.
These tools, shaped like a dog bone, are made from commercially-available polycaprolactone and include an inner strip of spiropyran polymer. When the research team yanked on one end of the sensor, it was permanently deformed and the strip inside turned purple.
The “bones” were made to record the maximum amount of force applied to the material by embedding four squares of spiropyran polymer, and by taking into account the length of the devices – and the amount of force applied – researchers found they could match the applied force to an observed change in the color of the strips. As they experimented with various combinations of materials and applied force, they say they could quickly correlate the force by simply counting the number of purple squares which appeared.
Called photo and mechanochromic 3D printed structures, the team used a fused filament fabrication printer to print ‘single and multicomponent tensile strength testing pieces.’ They say it would be difficult “if not impossible” to make the sensors using traditional manufacturing techniques which might degrade the spiropyran units or polymer chains. Since such functional polymers can change their shape or chemical composition when subjected to outside factors like light, heat, and mechanical force, they might prove ideal as sensors or for use in drug delivery systems.
But the researchers say common manufacturing techniques which involve light or heat can trigger the functional aspects of the materials prematurely, posing a significant problem.
In the past, researchers used molds to shape the functional polymers, but the process ultimately limits them in regard to the shape and complexity of structures they can create. So team lead Andrew J. Boydston of the University of Washington used 3D printing to create the necessary shapes.
To begin the work, the team developed a mechanosensitive polymer which could withstand being extruded by a commercial 3D printer – without changing color or being damaged – by the heat of the printing process. They then synthesized polycaprolactone polymers which contained 50% spiropyran, and when mechanical force is applied to spiropyran, it can isomerize to make a purple merocyanine.
Boydston says that, while a 3D printer can make the devices quickly and accurately, such constructs – which include squares of one polymer embedded inside another material – would be next to impossible to create inside molds.
What methods do you see scientists using to create devices which would be impossible to make with common manufacturing techniques and what applications do you see for 3D printing in the sciences going forward. Weigh in with your take and comment in the Shaped 3D Printed Polymers forum thread on 3DPB.com.